The heat pipes used in solar collectors have a boiling point of only 30oC (86oF). So when the heat pipe is heated above 30oC (86oF) the water vaporizes. This va pour rapidly rises to the top of the heat pipe transferring heat. As the heat is lost at the condenser (top), the va pour condenses to form a liquid (water) and returns to the bottom of the heat pipe to once again repeat the process.
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